It will be Blonde Night at Madison Square Garden when the World’s Most Famous Arena holds its annual tennis event in late February/early March.

The Post has learned Maria Sharapova will headline the BNP Paribas-sponsored event and face the U.S. Open’s No. 1 seed, Caroline Wozniacki of Denmark.

The men’s match, according to a person familiar with the Garden’s negotiations, is expected to be Roger Federer vs. Andy Roddick. The renovated Garden has not announced the card.

Last winter, the Garden tennis card went with a old-timer doubleheader: Andre Agassi vs. Pete Sampras and McEnroe vs. Ivan Lendl.