A man was shot and killed outside a Queens deli early Wednesday, cops said.

The 39-year-old victim, who has not yet been identified, entered the 7 & 7 Deli & Supermarket at the corner of 162nd Street and Station Road in Flushing around 12 a.m., police said.

When he left the store around 12:05 a.m., he was approached by an unknown man, who fired a round into his face, then fled west on Station Road, cops said.

The victim was pronounced dead at the scene.

Cops are searching for the suspect, who was last seen wearing a dark hooded sweatshirt.