A woman shot her husband in the eye, killing him in their Brooklyn apartment, cops said Saturday.

Tiffany Brown, 27, blasted Robert Bosalavage, 39, in the bedroom of their Flatlands home on Avenue K near East 39th Street around 5 a.m. Friday, police said.

Bosalavage was rushed to Kings County Hospital, where he later died.

Brown had called 911 to report her husband had been shot, but she did not fess up to the crime, cops said. She was charged Friday night with murder and criminal possession of a loaded firearm.

Her motive was unclear Saturday morning.

The couple did not have any children together, and no one else was in the home at the time of the shooting.